Poster

P2.15 – Lignin: Towards UV-Curable Coatings

Louise Brandt

KTH Royal Institute of Technology / WWSC

Co-author(s):
Arnaud  Barthelmé, Fiber and Polymer Technology, KTH Royal Institute of Technology
Maria Karlsson, Fiber and Polymer Technology, KTH Royal Institute of Technology
Mats Johansson, Wallenberg Wood Science Center, Fiber and Polymer Technology, KTH Royal Institute of Technology

Coatings are essential in modern society, providing protection, aesthetics, and functionality to various materials. Chemically cross-linked thermosetting materials are widely used for their mechanical strength and stability against chemicals and high temperatures [1]. UV-induced curing of these materials is efficient in energy consumption, reaction time, and reducing volatile organic compound (VOC) emissions [2]. While UV-curable coatings are popular for wood, glass, and plastic [3-7], their application on metal is limited due to poor adhesion, which is vital for corrosion protection [8]. Thus, improving adhesion between UV-curable coatings and metals is crucial for corrosion prevention. 
Lignin, a bio-based compound from wood, offers excellent anti-corrosion properties and adhesion to metals [9, 10]. Its aromatic structure adds rigidity, and its hydroxyl functional groups allow for material modification and tailoring of material properties [11]. However, conventional technical lignins absorb UV light, complicating their use in UV-curable formulations [12] and synthesis of UV-curable coatings with a high lignin content remains scarce. 
This study explores a novel lignin isolated through a cyclic organosolv process, which is less colored and has lower UV absorption than conventional technical lignins [13, 14]. UV-curable films were created by functionalizing the lignin with diallyl carbonate and using UV-induced thiol-ene chemistry for cross-linking. Characterization techniques such as NMR, SEC, and FTIR confirmed successful functionalization and the formation of thermoset films containing 68% functionalized lignin. Mechanical testing indicated that curing parameters significantly affect the films’ thermomechanical properties. These results highlight the potential of modified lignin for sustainable, high-performance UV-curable coatings, paving the way for broader applications in corrosion protection and beyond.

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