Industrial pulp and paper process represent a large market that can allow the use of by-product to avoid waste production and reduce pollution. Lignin represents the most available side product that can be used to produce bio-based monomer [1].In this study different ligning-derived biobased monomers have been synthesized and exploited both in cationic and radical UV-Curing [2]. Reactivity of curing process was investigated, and the crosslinked materials fully characterized. An easy tailoring of the properties of the final UV-cured coatings is demonstrated by varying the ratio of the monofunctional-difunctional epoxy monomer or by in-situ generation of hybrid organic-inorganic networks. The same formulations were processed in 3D-printing using the hot-lithography technique when processing epoxy monomers [3]. Finally, UV-Cured composites were achieved by exploiting the frontal induced photopolymerization process [4].